AUTHORS: Taiwo OO, Paz-García JM, Hall SA, Heenan TMM, Finegan DP, Mokso R, Villanueva-Pérez P, Patera A, Brett DJL, Shearing PR

Journal of Power Sources, 342: 904-912, February 2017

ABSTRACT

Due to their high theoretical capacity compared to that of state-of-the-art graphite-based electrodes, silicon electrodes have gained much research focus for use in the development of next generation lithium-ion batteries. However, a major drawback of silicon as an electrode material is that it suffers from particle fracturing due to huge volume expansion during electrochemical cycling, thus limiting commercialization of such electrodes. Understanding the role of material microstructure in electrode degradation will be instrumental in the design of stable silicon electrodes. Here, we demonstrate the application of synchrotron-based X-ray tomographic microscopy to capture and track microstructural evolution, phase transformation and fracturing within a silicon-based electrode during electrochemical lithiation.

Download PDF

BibTex

Module: